Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation.
نویسندگان
چکیده
Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(L-lactide)-b-poly(δ-valerolactone) in a 'one-pot' reaction.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 12 شماره
صفحات -
تاریخ انتشار 2013